一种高价态的二μ-氧代二锰配合物共价锚定在金属有机框架中，作为一种高效且可回收的水氧化催化剂。
A high-valent di-μ-oxo dimanganese complex covalently anchored in a metal-organic framework as a highly efficient and recoverable water oxidation catalyst.
作者信息
Zhang Lina, Chen Junying, Fan Ting, Shen Kui, Jiang Miao, Li Yingwei
机构信息
State Key Laboratory of Pulp and Paper Engineering, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.
出版信息
Chem Commun (Camb). 2018 Apr 19;54(33):4188-4191. doi: 10.1039/c8cc00258d.
PMID:29629466
Abstract
A biomimetic di-μ-oxo dimanganese complex bearing two triazole-binding tridentate ligands is successfully anchored inside a metal-organic framework (MOF) through a covalent-functionalization-assisted coordination strategy, exhibiting high activity and reliable durability in the chemical water oxidation reaction.
摘要
一种带有两个三唑结合三齿配体的仿生双μ-氧代二锰配合物通过共价功能化辅助配位策略成功锚定在金属有机框架（MOF）内，在化学水氧化反应中表现出高活性和可靠的耐久性。
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