Bu Naijing, Wu Jun, Zhen Qiang
J Nanosci Nanotechnol. 2017 Jan;17(1):766-72. doi: 10.1166/jnn.2017.12833.
The quartz abundant elutrilithe with several other elements from Pan zhihua, was taken as the main material to synthesize activated carbon-4A zeolite composite by hydrothermal crystallization after alkali fusion at 750 °C for 1 h under a flowing N2 atmosphere. Then the effect of alkali content and molar ratio of H2O versus Na2O on product was investigated, respectively. Finally, the activated carbon-4A zeolite composite was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), thermogravimetry-differential scanning calorimetry (TG-DSC). The results showed that the crystallization product was activated carbon-4A zeolite composite with complete crystal form and the average particle size was about 1 μm. Moreover, the composite materials had well adsorption capacities to water, hexane and metal ions such as Cu2+, Ni2+, Zn2+ and Pb2+ analyzing by inductively coupled plasma atomic emission spectrometry (ICP).
以攀枝花富含石英的漂积岩及其他几种元素为主要原料,在750℃、流动氮气气氛下碱熔1小时后,通过水热晶化合成活性炭-4A分子筛复合材料。然后分别考察了碱含量以及水与氧化钠的摩尔比对产物的影响。最后,采用X射线衍射(XRD)、扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)、热重-差示扫描量热法(TG-DSC)对活性炭-4A分子筛复合材料进行表征。结果表明,结晶产物为晶形完整的活性炭-4A分子筛复合材料,平均粒径约为1μm。此外,通过电感耦合等离子体原子发射光谱法(ICP)分析可知,该复合材料对水、己烷以及Cu2+、Ni2+、Zn2+和Pb2+等金属离子具有良好的吸附能力。