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硫功能化三维石墨烯整体材料作为用于超快钠离子存储的高性能阳极

Sulfur-functionalized three-dimensional graphene monoliths as high-performance anodes for ultrafast sodium-ion storage.

作者信息

Zheng Dequn, Zhang Jun, Lv Wei, Cao Tengfei, Zhang Siwei, Qiu Dong, Tao Ying, He Yanbing, Kang Feiyu, Yang Quan-Hong

机构信息

Engineering Laboratory for Functionalized Carbon Materials, Shenzhen Key Laboratory for Graphene-based Materials, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China.

出版信息

Chem Commun (Camb). 2018 Apr 24;54(34):4317-4320. doi: 10.1039/c8cc01631c.

Abstract

Sulfur-functionalized graphene monoliths with a high sulfur fraction (16.8 wt%) were prepared to demonstrate a high capacity (∼400 mA h g-1 at 0.1 A g-1) and ultrafast (∼120 mA h g-1 at 5 A g-1) sodium ion storage. The reversible reaction of -C-Sx-C- with sodium ions contributes to the extra capacity while a 3D graphene network guarantees high rate capability.

摘要

制备了具有高硫含量(16.8 wt%)的硫功能化石墨烯整体材料,以展示其高容量(在0.1 A g-1时约为400 mA h g-1)和超快的钠离子存储能力(在5 A g-1时约为120 mA h g-1)。-C-Sx-C-与钠离子的可逆反应有助于提供额外的容量,而三维石墨烯网络则保证了高倍率性能。

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