使用微波流动反应器选择性、可扩展合成 C60/茚单加成物。
Selective, Scalable Synthesis of C-Fullerene/Indene Monoadducts Using a Microwave Flow Applicator.
机构信息
National Institute of Advanced Industrial Science and Technology , Tsukuba Central 5, 1-1-1 Higashi , Tsukuba , Ibaraki 305-8568 , Japan.
SAIDA FDS, INC. , 143-10 Isshiki , Yaizu , Shizuoka 425-0054 , Japan.
出版信息
J Org Chem. 2018 Apr 20;83(8):4348-4354. doi: 10.1021/acs.joc.7b03209. Epub 2018 Apr 11.
The synergy of continuous processing and microwave heating technologies has unlocked scalable (g/h), safe and efficient reaction conditions for synthesis of fullerene/indene-based organic photovoltaic acceptor materials in a nonchlorinated solvent with levels of productivity unparalleled by previous syntheses. The microwave flow reactor sustains high temperature while employing short residence times, reaction conditions which uniquely allow the selective synthesis of fullerene/indene monoadducts. Design of experiments analysis revealed residence time as the most crucial factor for conversion and selectivity control.
连续处理和微波加热技术的协同作用，为富勒烯/茚基有机光伏受体材料的合成在非氯化溶剂中提供了可扩展（克/小时）、安全且高效的反应条件，其生产水平前所未有。微波流动反应器在采用短停留时间的同时保持高温，这种反应条件独特地允许富勒烯/茚单加成物的选择性合成。实验设计分析表明，停留时间是转化率和选择性控制的最关键因素。
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