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铁（MCP）配合物作为限制试剂催化烯烃与氮丙啶的偶联反应。

Iron(MCP) Complexes Catalyze Aziridination with Olefins As Limiting Reagents.

机构信息

Duke University , Department of Chemistry , Box 90346, Durham , North Carolina 27708-0354 , United States.

出版信息

J Org Chem. 2018 May 4;83(9):5072-5081. doi: 10.1021/acs.joc.8b00402. Epub 2018 Apr 25.

DOI:10.1021/acs.joc.8b00402
PMID:29648809
Abstract

Herein described are the first efficient nitrogen-atom transfer reactions mediated by iron N, N'-dimethyl- N, N'-bis(2-pyridinylmethyl)cyclohexane-1,2-diamine- (MCP-) and 2-({1-[(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine-type (PDP-type) complexes. These catalysts affect styrene aziridination under mild conditions based on a limiting quantity of olefin substrate.

摘要

本文描述了首例由铁 N，N'-二甲-N，N'-双(2-吡啶基甲基)环己烷-1,2-二胺-(MCP-)和 2-({1-[(吡啶-2-基甲基)吡咯烷-2-基]吡咯烷-1-基}甲基)吡啶型(PDP-型)配合物介导的高效氮原子转移反应。这些催化剂在温和条件下基于烯烃底物的限量影响苯乙烯氮丙啶化。

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