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用于摩托车尾气的冷压烧结法制备铋锑碲热电材料

Fabrication of Bi–Sb–Te Thermoelectric by Cold-Pressed Sintering for Motorcycle Exhaust.

作者信息

Kao Mu-Jung, Chen Ming-Jing

出版信息

J Nanosci Nanotechnol. 2017 Apr;17(4):2550-553. doi: 10.1166/jnn.2017.13368.

DOI:10.1166/jnn.2017.13368
PMID:29652124
Abstract

This study was conducted on the Bi–Sb–Te thermoelectric material which is cold-pressed Sintering under 750 Mpa to make square thermoelectric pairs with size 8.2 mm × 8.2 mm and thicknesses 0.8 mm and 1.5 mm. The zone melting method was used to acquire P-type thermoelectric material Bi0.4Sb1.6Te3 and N-type thermoelectric material Bi2Te2.5Se0.5. At temperature 383 K, the measured Seebeck coefficient of Bi0.4Sb1.6Te3 is 222 μV/K, and its thermoelectric figure of merit ZT is 1.35. At temperature 400 K, the measured Seebeck coefficient of Bi2Te2.5Se0.5 is 210 μV/K, and its thermoelectric figure of merit ZT is 1.13. Using Solder paste Sn42Bi58 and copper electrode plate are in series connection with 16 pieces of P/N thermoelectric material to form thermoelectric modules. The thermoelectric module is actually pasted on the motorcycle waste heat source to be evaluated the performance, making the cold-end temperature dissipation heat can enhance the temperature difference between it so as to increase the output power. Increasing the leg thickness of thermoelectric module and making the about 35 °C temperature-difference of those can obviously enhance the performance of in terms of its voltage, its thermoelectric figure of merit ZT and output power of the thermoelectric modules.

摘要

本研究是在Bi–Sb–Te热电材料上进行的,该材料在750兆帕的压力下冷压烧结,制成尺寸为8.2毫米×8.2毫米、厚度为0.8毫米和1.5毫米的方形热电对。采用区熔法获得P型热电材料Bi0.4Sb1.6Te3和N型热电材料Bi2Te2.5Se0.5。在383K温度下,测得Bi0.4Sb1.6Te3的塞贝克系数为222μV/K,其热电优值ZT为1.35。在400K温度下,测得Bi2Te2.5Se0.5的塞贝克系数为210μV/K,其热电优值ZT为1.13。使用焊膏Sn42Bi58和铜电极板与16片P/N热电材料串联连接形成热电模块。将热电模块实际粘贴在摩托车废热源上以评估其性能,使冷端温度散热能够提高其温差,从而增加输出功率。增加热电模块的腿厚并使其温差约为35°C,可以显著提高热电模块在电压、热电优值ZT和输出功率方面的性能。

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