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含聚二甲基硅氧烷侧链的二酮吡咯并吡咯基聚合物的合成及其在有机场效应晶体管中的应用。

Synthesis of diketopyrrolopyrrole-based polymers with polydimethylsiloxane side chains and their application in organic field-effect transistors.

作者信息

Ohnishi Inori, Hashimoto Kazuhito, Tajima Keisuke

机构信息

RIKEN Center for Emergent Matter Science (CEMS), 2-1 Hirosawa, Wako 351-0198, Japan.

Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.

出版信息

R Soc Open Sci. 2018 Mar 14;5(3):172025. doi: 10.1098/rsos.172025. eCollection 2018 Mar.

DOI:10.1098/rsos.172025
PMID:29657801
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5882725/
Abstract

Linear polydimethylsiloxane (PDMS) was investigated as a solubilizing group for π-conjugated polymers with the aim of combining high solubility in organic solvents with the molecular packing in solid films that is advantageous for charge transport. Diketopyrrolopyrrole-based copolymers with different contents and substitution patterns of the PDMS side chains were synthesized and evaluated for application in organic field-effect transistors. The PDMS side chains greatly increased the solubility of the polymers and led to shorter -spacings of the π-stacking in the thin films compared with polymers containing conventional branched alkyl side chains.

摘要

研究了线性聚二甲基硅氧烷（PDMS）作为π共轭聚合物的增溶基团，目的是将其在有机溶剂中的高溶解性与有利于电荷传输的固体薄膜中的分子堆积相结合。合成了具有不同PDMS侧链含量和取代模式的基于二酮吡咯并吡咯的共聚物，并评估了其在有机场效应晶体管中的应用。与含有传统支链烷基侧链的聚合物相比，PDMS侧链大大提高了聚合物的溶解性，并导致薄膜中π堆积的间距更短。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0d8/5882725/a0f16b2db66a/rsos172025-g4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0d8/5882725/e17003483718/rsos172025-g1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0d8/5882725/fea3c3f6c8bf/rsos172025-g2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0d8/5882725/8ddf2e5b3aad/rsos172025-g3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0d8/5882725/a0f16b2db66a/rsos172025-g4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0d8/5882725/e17003483718/rsos172025-g1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0d8/5882725/fea3c3f6c8bf/rsos172025-g2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0d8/5882725/8ddf2e5b3aad/rsos172025-g3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0d8/5882725/a0f16b2db66a/rsos172025-g4.jpg

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2
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3
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J Am Chem Soc. 2013 Oct 9;135(40):14896-9. doi: 10.1021/ja405112s. Epub 2013 Sep 25.
4
Efficient small bandgap polymer solar cells with high fill factors for 300 nm thick films.高效小带隙聚合物太阳能电池，具有高填充因子，适用于 300nm 厚的薄膜。
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6
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7
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