Demekhin Evgeny A, Ganchenko Georgy S, Gorbacheva Ekaterina V, Amiroudine Sakir
Laboratory of Micro- and Nanoscale Electro- and Hydrodynamics, Financial University under the Government of the Russian Federation, Krasnodar, Russian Federation.
Laboratory of General Aeromechanics, Institute of Mechanics, Moscow State University, Moscow, Russian Federation.
Electrophoresis. 2018 Apr 16. doi: 10.1002/elps.201700472.
The stability of the electroosmotic flow of the two-phase system electrolyte-dielectric with a free interface in the microchannel under an external electric field is examined theoretically. The mathematical model includes the Nernst-Plank equations for the ion concentrations. The linear stability of the 1D nonstationary solution with respect to the small, periodic perturbations along the channel, is studied. Two types of instability have been highlighted. The first is known as the long-wave instability and is connected with the distortion of the free charge on the interface. In the long-wave area, the results are in good agreement with the ones obtained theoretically and experimentally in the literature. The second type of instability is a short-wave and mostly connected with the disturbance of the electrolyte conductivity. The short-wave type of instability has not been found previously in the literature and constitutes the basis and the strength of the present work. It is revealed that with the increase of the external electric field frequency, the 1D flow is stabilized. The dependence of the flow on the other parameters of the system is qualitatively the same as for the constant electric field.
从理论上研究了微通道中具有自由界面的两相系统电解质 - 电介质在外加电场作用下电渗流的稳定性。数学模型包括离子浓度的能斯特 - 普朗克方程。研究了一维非定常解相对于沿通道的小周期扰动的线性稳定性。突出了两种类型的不稳定性。第一种称为长波不稳定性,与界面上自由电荷的畸变有关。在长波区域,结果与文献中理论和实验得到的结果吻合良好。第二种不稳定性是短波,主要与电解质电导率的扰动有关。短波型不稳定性以前在文献中未被发现,是本工作的基础和优势所在。结果表明,随着外加电场频率的增加,一维流动趋于稳定。流动对系统其他参数的依赖性在定性上与恒定电场的情况相同。