从硅烷可扩展合成氢化二硅氧烷：由苯基硅烷一锅法制备1,3 - 二苯基二硅氧烷。
Scalable Synthesis of Hydrido-Disiloxanes from Silanes: A One-Pot Preparation of 1,3-Diphenyldisiloxane from Phenylsilane.
作者信息
Buonomo Joseph A, Eiden Carter G, Aldrich Courtney C
机构信息
University of Minnesota, Department of Medicinal Chemistry, Weaver-Densford Hall, 308 Harvard St. SE Minneapolis, MN 55455, USA.
出版信息
Synthesis (Stuttg). 2018 Jan;50(2):278-281. doi: 10.1055/s-0036-1588580. Epub 2017 Sep 26.
Abstract
A simple, one-pot, and high-yielding synthesis of 1,3-diphenyldisiloxane is presented. The preparation of similar symmetrical disiloxane materials is also accomplished with this same protocol. This mechano-chemical procedure is efficient and highly scalable, furnishing a convenient route to hydrido-disiloxanes from widely accessible commercially available silanes.
摘要
本文介绍了一种简单、一锅法且高产率合成1,3-二苯基二硅氧烷的方法。使用相同的方案也可完成类似对称二硅氧烷材料的制备。这种机械化学方法高效且具有高度可扩展性，为从广泛可得的市售硅烷制备氢化二硅氧烷提供了一条便捷途径。
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