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竞争阳离子-π 和外墙面 π-π 相互作用:实现超灵敏响应的新方法。

Competition of cation-π and exo-wall π-π interactions: a novel approach to achieve ultrasensitive response.

机构信息

Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, P. R. China.

出版信息

Chem Commun (Camb). 2018 May 1;54(36):4549-4552. doi: 10.1039/c8cc00814k.

DOI:10.1039/c8cc00814k
PMID:29662974
Abstract

A novel approach to achieve ultrasensitive response was successfully developed by rationally introducing the competition between cation-π and exo-wall π-π interactions into a pillar[5]arene-based supramolecular organogel (P5N-OG). Interestingly, the P5N-OG could be used for ion detection and separation, fluorescent display materials as well as ultrasensitive logic gates.

摘要

通过合理引入阳离子-π和外骨架 π-π 相互作用之间的竞争,成功开发了一种实现超灵敏响应的新方法,该方法基于柱芳烃的超分子有机凝胶(P5N-OG)。有趣的是,P5N-OG 可用于离子检测和分离、荧光显示材料以及超灵敏逻辑门。

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