三氟乙酸碘苯（III）（PIFA）介导的水中芳基硫醚的合成

Phenyliodine(III) Bis(trifluoroacetate) (PIFA)-Mediated Synthesis of Aryl Sulfides in Water.

作者信息

Feng Qingyuan, Chen Dengfeng, Hong Mei, Wang Fei, Huang Shenlin

机构信息

Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-Forest Biomass, College of Chemical Engineering , Nanjing Forestry University , Nanjing 210037 , P. R. China.

Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources , Nanjing Forestry University , Nanjing 210037 , P. R. China.

出版信息

J Org Chem. 2018 Jul 20;83(14):7553-7558. doi: 10.1021/acs.joc.8b00435. Epub 2018 Apr 27.

DOI:10.1021/acs.joc.8b00435

PMID:29664643

Abstract

An environmentally benign method for the synthesis of aryl sulfides in water under mild conditions has been realized, in which arenes are coupled with equal stoichiometry of allyl sulfides. This arylthiolation is enabled by the presence of the Lipshutz surfactant, TPGS-750-M, using water as the recyclable reaction medium.

摘要

已实现一种在温和条件下于水中合成芳基硫醚的环境友好方法，其中芳烃与化学计量比相等的烯丙基硫醚偶联。这种芳基硫醇化反应通过Lipshutz表面活性剂TPGS - 750 - M的存在得以实现，使用水作为可循环利用的反应介质。