School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
EaStCHEM, School of Chemistry, University of Edinburgh, Joseph Black Building, The King's Buildings, David Brewster Road, Edinburgh, EH9 3FJ, UK.
Chemistry. 2018 Jun 12;24(33):8315-8319. doi: 10.1002/chem.201801804. Epub 2018 May 15.
The enantioselective Cu-catalyzed 1,6-boration of (E,E)-α,β,γ,δ-unsaturated ketones is described, which gives homoallylic boronates with high enantiomeric purity and unexpectedly high Z-selectivity. By changing the solvent, the outcome can be altered to give E-allylic boronates.
手性铜催化的（E,E）-α,β,γ,δ-不饱和酮的 1,6-硼化反应被描述，该反应以高对映纯度和出人意料的高 Z-选择性得到偕烯丙基硼酸酯。通过改变溶剂，可以改变反应结果得到 E-烯丙基硼酸酯。
