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Catalytic Enantioselective Synthesis of Allylic Boronates Bearing a Trisubstituted Alkenyl Fluoride and Related Derivatives.
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Switchable Synthesis of Z-Homoallylic Boronates and E-Allylic Boronates by Enantioselective Copper-Catalyzed 1,6-Boration.
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γ-, Diastereo-, and Enantioselective Addition of MEMO-Substituted Allylboron Compounds to Aldimines Catalyzed by Organoboron-Ammonium Complexes.
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Hydrocyclization/Defluorination of CF-Substituted Acrylamides: Insights from Kinetics of Hydrogen Atom Transfer.
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Synthesis of --Cl,CF-Substituted Alkenes by Stereoselective Cross-Metathesis and the Role of Disubstituted Mo Alkylidenes.
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Copper-Catalyzed Regio- and Enantioselective Hydroboration of Difluoroalkyl-Substituted Internal Alkenes.
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Nickel-catalyzed enantioselective α-heteroarylation of ketones C-F bond activation to construct all-carbon quaternary stereocenters.
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Electrochemical Synthesis of gem-Difluoro- and γ-Fluoro-Allyl Boronates and Silanes.
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Organocatalytic Nucleophilic Substitution Reaction of gem-Difluoroalkenes with Ketene Silyl Acetals.
Org Lett. 2019 Apr 5;21(7):2277-2280. doi: 10.1021/acs.orglett.9b00566. Epub 2019 Mar 12.
2
Hydrogen Bonding Phase-Transfer Catalysis with Potassium Fluoride: Enantioselective Synthesis of β-Fluoroamines.
J Am Chem Soc. 2019 Feb 20;141(7):2878-2883. doi: 10.1021/jacs.8b12568. Epub 2019 Feb 4.
3
Enantioselective Synthesis of Tertiary Allylic Fluorides by Iridium-Catalyzed Allylic Fluoroalkylation.
Angew Chem Int Ed Engl. 2018 Oct 1;57(40):13125-13129. doi: 10.1002/anie.201807474. Epub 2018 Sep 11.
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Activation of C-F bonds α to C-C multiple bonds.
Chem Commun (Camb). 2018 Sep 11;54(73):10224-10239. doi: 10.1039/c8cc05108a.
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Enolizable β-Fluoroenones: Synthesis and Asymmetric 1,2-Reduction.
Org Lett. 2018 Aug 17;20(16):5071-5074. doi: 10.1021/acs.orglett.8b02435. Epub 2018 Aug 7.
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Recent advances in the synthesis of functionalised monofluorinated compounds.
Chem Commun (Camb). 2018 Aug 28;54(70):9706-9725. doi: 10.1039/c8cc05181j.
7
Transition-Metal-Mediated and -Catalyzed C-F Bond Activation by Fluorine Elimination.
Angew Chem Int Ed Engl. 2019 Jan 8;58(2):390-402. doi: 10.1002/anie.201805292. Epub 2018 Nov 8.
10
Tyr-ψ[( Z)CF═CH]-Gly Fluorinated Peptidomimetic Improves Distribution and Metabolism Properties of Leu-Enkephalin.
ACS Chem Neurosci. 2018 Jul 18;9(7):1735-1742. doi: 10.1021/acschemneuro.8b00085. Epub 2018 Apr 19.

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