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不同高体积分数碳化硅颗粒对铋酸盐玻璃-碳化硅/铝复合材料界面的影响。

Effect of the Different High Volume Fraction of SiC Particles on the Junction of Bismuthate Glass-SiC/Al Composite.

作者信息

Wang Bin, Qu Shengguan, Li Xiaoqiang

机构信息

Guangdong Key Laboratory for Processing and Forming of Advanced Metallic Materials, South China University of Technology, Guangzhou 510640, China.

National Engineering Research Center of Near-Net-Shape Forming for Metallic Materials, South China University of Technology, Guangzhou 510640, China.

出版信息

Scanning. 2018 Feb 20;2018:7394040. doi: 10.1155/2018/7394040. eCollection 2018.

Abstract

The in-house developed bismuthate glass and the SiC/Al composites with different volume fractions of SiC particles (namely, 60 vol.%, 65 vol.%, 70 vol.%, and 75 vol.%) were jointed by vacuum hot-pressing process. The novel material can be used for the space mirror. The SiCp is an abbreviation for SiC particle. Firstly, the SiC/Al composites with different vol.% of SiC particle were manufactured by using infiltration process. In order to obtain a stable bonding interface, the preoxide layers were fabricated on the surfaces of these composites for reacting with the bismuthate glass. The coefficient of thermal expansion (CTE) was carried out for characterizing the difference between the composites and bismuthate glass. The sealing quality of the composites and the bismuthate glass was quantified by using shear strength testing. The optical microstructures showed the particles were uniformly distributed in the Al matrix. The SEM image shows that a smooth oxidation layer was generated on the SiC/Al composite. The CTE testing result indicated that the higher the vol.% of the particles in the composite, the lower the CTE value. The shear strength testing result disclosed that SiC/Al composite with relatively low CTE value was favorable to obtain a bonding interface with high strength.

摘要

通过真空热压工艺将内部研发的铋酸盐玻璃与具有不同体积分数SiC颗粒(即60体积%、65体积%、70体积%和75体积%)的SiC/Al复合材料进行连接。这种新型材料可用于空间镜。SiCp是SiC颗粒的缩写。首先,采用浸渗工艺制造具有不同体积%SiC颗粒的SiC/Al复合材料。为了获得稳定的结合界面,在这些复合材料的表面制备预氧化层,以便与铋酸盐玻璃发生反应。通过热膨胀系数(CTE)来表征复合材料与铋酸盐玻璃之间的差异。利用剪切强度测试对复合材料与铋酸盐玻璃的密封质量进行量化。光学微观结构显示颗粒均匀分布在Al基体中。扫描电子显微镜图像表明在SiC/Al复合材料上生成了一层光滑的氧化层。CTE测试结果表明,复合材料中颗粒的体积%越高,CTE值越低。剪切强度测试结果表明,具有相对较低CTE值的SiC/Al复合材料有利于获得高强度的结合界面。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/466a/5838495/cf42c9bd4646/SCANNING2018-7394040.001.jpg

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