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二元纳米复合塑料薄膜中高效的蓝光到红光余辉调谐

Efficient Blue to Red Afterglow Tuning in a Binary Nanocomposite Plastic Film.

作者信息

Xia Yan, Ou Huase, Li Wanbin, Han Gang, Li Zhanjun

机构信息

Guangdong Key Laboratory of Environmental Pollution and Health, School of Environment, Jinan University, Guangzhou 510632, China.

Department of Biochemistry and Molecular Pharmacology, University of Massachusetts Medical School, Worcester, MA 01605, USA.

出版信息

Nanomaterials (Basel). 2018 Apr 20;8(4):260. doi: 10.3390/nano8040260.

Abstract

Colorful spectra are important for the diverse applications of persistent phosphors. A color conversion concept is developed to obtain abundant persistent luminescence color by mining capacities of known persistent phosphors with the most efficient persistent properties. Here, SiO₂/Sr₂MgSi₂O₇:Eu,Dy nanoparticles are chosen as a blue persistent luminescence donor nanophosphor, while ultrafine CaAlSiN₃:Eu is utilized as a red conversion phosphor to tune the persistent luminescence spectra from blue to red. The red afterglow emission can persist for more than 5 h. The decay of the red afterglow follows nearly the same kinetics as that of the blue one. Continuous color tuning can be successfully obtained by simply changing the mass ratio of the donor/conversion phosphor pair. This color conversion strategy may be significant in indicating numerous persistent/conversion nanocomposites or nanostructures and advance the development of persistent phosphors in diverse fields which need colorful spectral properties.

摘要

多彩光谱对于持久磷光体的多种应用至关重要。通过挖掘具有最有效持久性能的已知持久磷光体的能力,开发了一种颜色转换概念,以获得丰富的持久发光颜色。在此,选择SiO₂/Sr₂MgSi₂O₇:Eu,Dy纳米颗粒作为蓝色持久发光供体纳米磷光体,而超细CaAlSiN₃:Eu用作红色转换磷光体,以将持久发光光谱从蓝色调至红色。红色余辉发射可持续超过5小时。红色余辉的衰减遵循与蓝色余辉几乎相同的动力学。通过简单改变供体/转换磷光体对的质量比,可以成功实现连续的颜色调节。这种颜色转换策略对于指示众多持久/转换纳米复合材料或纳米结构可能具有重要意义,并推动持久磷光体在需要多彩光谱特性的不同领域的发展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/adb5/5923590/db9711a122ae/nanomaterials-08-00260-g001.jpg

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