Zhao Dan, Song Lijun, Hou Linxi
College of Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
ACS Omega. 2021 Sep 20;6(39):25585-25593. doi: 10.1021/acsomega.1c03670. eCollection 2021 Oct 5.
Developing an appropriate method to broaden the color of long persistent luminescence materials has important scientific significance and practical value but remains a great challenge. Herein, we have developed a unique strategy to fine-tune the persistent luminescence using the inclusion complex of rhodamine 6G with (2-hydroxypropyl)-β-cyclodextrin as efficient light conversion materials. The emitting color of the novel persistent luminescence material could be tuned from green to orange by changing the concentration of the light conversion agent. Furthermore, afterglow decay measurements showed that the initial afterglow brightness is 9.65 cd/m, and the initial afterglow brightness gradually decreased as the cyclodextrin inclusion compound coating increased. This design concept introduces a new perspective for broadening the luminescence color of afterglow phosphors, which may open up new opportunities for persistent luminescence materials toward many emerging applications.
开发一种合适的方法来拓宽长余辉发光材料的颜色具有重要的科学意义和实用价值,但仍然是一个巨大的挑战。在此,我们开发了一种独特的策略,使用罗丹明6G与(2-羟丙基)-β-环糊精的包合物作为高效光转换材料来微调余辉发光。通过改变光转换剂的浓度,新型余辉发光材料的发射颜色可以从绿色调至橙色。此外,余辉衰减测量表明,初始余辉亮度为9.65 cd/m²,并且随着环糊精包合物涂层的增加,初始余辉亮度逐渐降低。这一设计理念为拓宽余辉磷光体的发光颜色引入了新的视角,这可能为余辉发光材料在许多新兴应用中开辟新的机遇。