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用于质谱分析的快速喷发解吸电离

Fast Eruption Desorption Ionization for Mass Spectrometric Analysis.

作者信息

Liu Xiao-Pan, Wang Hao-Yang, Dong Guo-Qing, Li Zhong-Quan, Guo Yin-Long

机构信息

State Key Laboratory of Organometallic Chemistry and National Center for Organic Mass Spectrometry in Shanghai, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 20032, China.

出版信息

J Am Soc Mass Spectrom. 2018 Jun;29(6):1319-1322. doi: 10.1007/s13361-018-1962-6. Epub 2018 Apr 20.

DOI:10.1007/s13361-018-1962-6
PMID:29679286
Abstract

Fast eruption desorption ionization (FEDI) technique was developed for simple, rapid, and sensitive analysis of various compounds. The FEDI allows three analytical modes each with the unique characteristic. The results demonstrated that non-assisted eruption was suitable for stable and volatile compounds, energetic material (EM)-assisted for nonvolatile molecules especially metal compounds, and solvent-assisted eruption for fragile molecules. High-quality mass spectra with intact ions of analytes were obtained in positive and negative ion modes. Graphical Abstract ᅟ.

摘要

快速喷发解吸电离(FEDI)技术是为各种化合物的简单、快速和灵敏分析而开发的。FEDI具有三种各具独特特性的分析模式。结果表明,非辅助喷发适用于稳定和挥发性化合物,含能材料(EM)辅助适用于非挥发性分子尤其是金属化合物,溶剂辅助喷发适用于易破碎分子。在正离子和负离子模式下均获得了含有完整分析物离子的高质量质谱图。图形摘要ᅟ。

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本文引用的文献

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Triboelectric nanogenerators for sensitive nano-coulomb molecular mass spectrometry.用于灵敏纳库仑分子质谱分析的摩擦电纳米发电机
Nat Nanotechnol. 2017 May;12(5):481-487. doi: 10.1038/nnano.2017.17. Epub 2017 Feb 27.
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Ambient Ionization Mass Spectrometry Measurement of Aminotransferase Activity.环境离子化质谱测定氨基转移酶活性。
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Real-Time Quantitative Analysis of Valproic Acid in Exhaled Breath by Low Temperature Plasma Ionization Mass Spectrometry.
低温等离子体电离质谱法实时分析呼出气中丙戊酸。
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Multifunctional Carbon Fiber Ionization Mass Spectrometry.多功能碳纤维离子化质谱。
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Direct and Convenient Mass Spectrometry Sampling with Ambient Flame Ionization.采用常压火焰离子化的直接便捷质谱采样
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Zero Volt Paper Spray Ionization and Its Mechanism.零电压纸喷雾电离及其机制。
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Solvent assisted inlet ionization: an ultrasensitive new liquid introduction ionization method for mass spectrometry.溶剂辅助进样离子化:一种用于质谱分析的超高灵敏度新型液体进样离子化方法。
Anal Chem. 2011 Jun 1;83(11):3981-5. doi: 10.1021/ac200556z. Epub 2011 May 9.
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New paradigm in ionization: multiply charged ion formation from a solid matrix without a laser or voltage.新的电离模式:无需激光或电压即可从固体基质中形成多电荷离子。
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10
Electrostatic charging due to separation of ions at interfaces: contact electrification of ionic electrets.由于界面处离子分离导致的静电充电:离子驻极体的接触起电
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