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基于纤维素的功能材料的拓扑化学工程。

Topochemical Engineering of Cellulose-Based Functional Materials.

机构信息

Laboratory of Fibre and Cellulose Technology , Åbo Akademi University , Porthansgatan 3 , FI-20500 , Åbo , Finland.

Department of Chemical Engineering , KU Leuven , Celestijnenlaan 200F bus 2424 , B-3001 Leuven , Belgium.

出版信息

Langmuir. 2018 Aug 28;34(34):9857-9878. doi: 10.1021/acs.langmuir.7b04379. Epub 2018 May 3.

DOI:10.1021/acs.langmuir.7b04379
PMID:29694048
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6151662/
Abstract

Topochemical engineering is a method of designing the fractionation (disassembly) and fabrication (assembly) of highly engineered functional materials using a combination of molecular and supramolecular techniques. Cellulose is one of the naturally occurring biopolymers, currently considered to be an important raw material for the design and development of sustainable products and processes. This feature article deals with new insights into how cellulose can be processed and functionalized using topochemical engineering in order to create functional fibers, enhance biopolymer dissolution in water-based solvents, and control the shaping of porous materials. Subsequently, topochemical engineering of cellulose offers a variety of morphological structures such as highly engineered fibers, functional cellulose beads, and reactive powders that find relevant applications in pulp bleaching, enzyme and antimicrobial drug carriers, ion exchange resins, photoluminescent materials, waterproof materials, fluorescent materials, flame retardants, and template materials for inorganic synthesis. The topochemical engineering of biopolymers and biohybrids is an exciting and emerging area of research that can boost the design of new bioproducts with novel functionalities and technological advancements for biobased industries.

摘要

拓扑化学工程是一种使用分子和超分子技术相结合的方法，用于设计高度工程化功能材料的分馏（拆卸）和制造（组装）。纤维素是一种天然存在的生物聚合物，目前被认为是设计和开发可持续产品和工艺的重要原料。本文介绍了如何使用拓扑化学工程对纤维素进行加工和功能化，以制造功能性纤维、增强生物聚合物在水基溶剂中的溶解能力以及控制多孔材料的成型，从而获得新的见解。随后，纤维素的拓扑化学工程提供了多种形态结构，如高度工程化纤维、功能性纤维素珠和反应性粉末，这些结构在纸浆漂白、酶和抗菌药物载体、离子交换树脂、光致发光材料、防水材料、荧光材料、阻燃剂以及无机合成的模板材料等方面有相关应用。生物聚合物和生物杂化材料的拓扑化学工程是一个令人兴奋和新兴的研究领域，可以促进具有新颖功能的新型生物产品的设计，并为生物基产业带来技术进步。

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