Organic Geochemistry Research Laboratory, U.S. Geological Survey, Lawrence, Kansas 66049, United States; Chemistry Department, University of Kansas, Lawrence, Kansas 66045, United States.
Organic Geochemistry Research Laboratory, U.S. Geological Survey, Lawrence, Kansas 66049, United States.
Sci Total Environ. 2018 Sep 15;636:212-219. doi: 10.1016/j.scitotenv.2018.04.246. Epub 2018 Apr 26.
The environmental fate of polyoxyethylene tallow amine (POEA), an additive in glyphosate herbicide formulations, has not been studied. This study examined the dissipation of POEA; glyphosate; and aminomethylphosphonic acid (AMPA), a degradation product of glyphosate, in the top 45 cm of soil from an agricultural field where glyphosate was applied. The concentration of these compounds was also analyzed in bed sediment samples from watersheds in agricultural and urban areas from six states (Georgia, Hawaii, Iowa, Mississippi, North Carolina, South Carolina). The field studies show that POEA, glyphosate, and AMPA persist on the soil from planting season to planting season but dissipate over time with little migration into deeper soil. POEA, glyphosate, and AMPA were found on the bed sediment samples in urban and agricultural watersheds.
聚氧乙烯牛脂胺(POEA)是草甘膦除草剂配方中的一种添加剂,其环境归宿尚未得到研究。本研究检测了在草甘膦施用农田的土壤顶层(45cm 深)中 POEA、草甘膦和氨甲基膦酸(AMPA,草甘膦的降解产物)的消解情况。还分析了来自六个州(佐治亚州、夏威夷州、爱荷华州、密西西比州、北卡罗来纳州、南卡罗来纳州)农业和城市流域床沉积物样本中这些化合物的浓度。田间研究表明,POEA、草甘膦和 AMPA 从种植季节到种植季节都残留在土壤中,但随着时间的推移会逐渐消解,很少迁移到深层土壤中。在城市和农业流域的床沉积物样本中发现了 POEA、草甘膦和 AMPA。