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高性能纯钨的选择性激光熔化:参数设计、致密化行为及力学性能

Selective laser melting of high-performance pure tungsten: parameter design, densification behavior and mechanical properties.

作者信息

Tan Chaolin, Zhou Kesong, Ma Wenyou, Attard Bonnie, Zhang Panpan, Kuang Tongchun

机构信息

School of Materials Science and Engineering, South China University of Technology, Guangzhou, China.

National Engineering Laboratory for Modern Materials Surface Engineering Technology, Guangdong Institute of New Materials, Guangzhou, China.

出版信息

Sci Technol Adv Mater. 2018 Apr 18;19(1):370-380. doi: 10.1080/14686996.2018.1455154. eCollection 2018.

DOI:10.1080/14686996.2018.1455154
PMID:29707073
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5917440/
Abstract

Selective laser melting (SLM) additive manufacturing of pure tungsten encounters nearly all intractable difficulties of SLM metals fields due to its intrinsic properties. The key factors, including powder characteristics, layer thickness, and laser parameters of SLM high density tungsten are elucidated and discussed in detail. The main parameters were designed from theoretical calculations prior to the SLM process and experimentally optimized. Pure tungsten products with a density of 19.01 g/cm (98.50% theoretical density) were produced using SLM with the optimized processing parameters. A high density microstructure is formed without significant balling or macrocracks. The formation mechanisms for pores and the densification behaviors are systematically elucidated. Electron backscattered diffraction analysis confirms that the columnar grains stretch across several layers and parallel to the maximum temperature gradient, which can ensure good bonding between the layers. The mechanical properties of the SLM-produced tungsten are comparable to that produced by the conventional fabrication methods, with hardness values exceeding 460 HV and an ultimate compressive strength of about 1 GPa. This finding offers new potential applications of refractory metals in additive manufacturing.

摘要

由于纯钨的固有特性,选择性激光熔化(SLM)增材制造纯钨几乎遇到了SLM金属领域的所有棘手难题。详细阐述并讨论了SLM高密度钨的关键因素,包括粉末特性、层厚和激光参数。主要参数在SLM工艺之前通过理论计算进行设计,并通过实验进行优化。采用优化后的工艺参数,通过SLM制备出了密度为19.01 g/cm(理论密度的98.50%)的纯钨产品。形成了高密度微观结构,没有明显的球化或宏观裂纹。系统地阐明了孔隙的形成机制和致密化行为。电子背散射衍射分析证实,柱状晶粒延伸穿过几层并平行于最大温度梯度,这可以确保层间的良好结合。SLM制备的钨的力学性能与传统制造方法制备的相当,硬度值超过460 HV,极限抗压强度约为1 GPa。这一发现为难熔金属在增材制造中的新潜在应用提供了可能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/ba1bdb24dd85/TSTA_A_1455154_F0008_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/46b0dabeb5f3/TSTA_A_1455154_UF0001_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/bd9d5bf36059/TSTA_A_1455154_F0001_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/21f5bcf03544/TSTA_A_1455154_F0002_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/ab1eaad3c50f/TSTA_A_1455154_F0003_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/176a0439e684/TSTA_A_1455154_F0004_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/2ef25b812dc4/TSTA_A_1455154_F0005_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/4654cb658396/TSTA_A_1455154_F0006_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/3663ce6f3229/TSTA_A_1455154_F0007_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/ba1bdb24dd85/TSTA_A_1455154_F0008_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/46b0dabeb5f3/TSTA_A_1455154_UF0001_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/bd9d5bf36059/TSTA_A_1455154_F0001_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/21f5bcf03544/TSTA_A_1455154_F0002_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/ab1eaad3c50f/TSTA_A_1455154_F0003_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/176a0439e684/TSTA_A_1455154_F0004_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/2ef25b812dc4/TSTA_A_1455154_F0005_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/4654cb658396/TSTA_A_1455154_F0006_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/3663ce6f3229/TSTA_A_1455154_F0007_OC.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d2/5917440/ba1bdb24dd85/TSTA_A_1455154_F0008_OC.jpg

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