新型异双核配合物中铑或钯与钕的金属-金属“通信”
Metal--Metal "Communication" of Rh or Pd with Nd in Novel Heterobinuclear Complexes.
作者信息
Spannenberg Anke, Oberthür Markus, Noss Henrik, Tillack Annegret, Arndt Perdita, Kempe Rhett
机构信息
Abt. Komplexkatalyse, Institut für Organische Katalyseforschung an der Universität, Buchbinderstrasse 5-6, D-18055 Rostock (Germany), Fax: (+49) 381-466-9374.
出版信息
Angew Chem Int Ed Engl. 1998 Aug 17;37(15):2079-2082. doi: 10.1002/(SICI)1521-3773(19980817)37:15<2079::AID-ANIE2079>3.0.CO;2-Y.
The reaction of a neodymium "ate" complex and an electron-rich transition metal chloride by salt elimination is an efficient method for synthesizing heterobinuclear compounds which contain a lanthanide and a Group 9 or 10 metal [Eq. (1), H Ap=2-amino-4-methylpyridine]. The use of bisaminopyridinato ligands allows extremely short distances between Rh or Pd and Nd.
通过消除盐的方式，使钕“酸根”配合物与富电子过渡金属氯化物发生反应，是合成含有镧系元素以及第9族或第10族金属的异双核化合物的有效方法[方程式(1)，H Ap = 2-氨基-4-甲基吡啶]。使用双氨基吡啶配体可使铑或钯与钕之间的距离极短。
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