Meier Herbert, Lehmann Matthias
Institut für Organische Chemie der Universität, J.-J. Becherweg 18-22, D-55099 Mainz (Germany), Fax: (+49) 6131 395-396.
Angew Chem Int Ed Engl. 1998 Mar 16;37(5):643-645. doi: 10.1002/(SICI)1521-3773(19980316)37:5<643::AID-ANIE643>3.0.CO;2-4.
A convergent synthesis in which all trans double bonds were constructed by Wittig-Horner reactions produces dendrimers of the general structure 1. With long-chain alkoxy residues on the periphery of the benzene rings, the first two generations display liquid crystalline behavior.
一种通过维蒂希-霍纳反应构建所有反式双键的汇聚合成法可生成具有通式1结构的树枝状大分子。由于苯环外围带有长链烷氧基残基，前两代呈现出液晶行为。
