大气氮的固定：以大气氮为氮源合成杂环化合物
Fixation of Atmospheric Nitrogen: Synthesis of Heterocycles with Atmospheric Nitrogen as the Nitrogen Source.
作者信息
Mori Miwako, Hori Katsutoshi, Akashi Masaya, Hori Masanori, Sato Yoshihiro, Nishida Mayumi
机构信息
Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060 (Japan), Fax: (+81) 11-721-6045.
出版信息
Angew Chem Int Ed Engl. 1998 Mar 16;37(5):636-637. doi: 10.1002/(SICI)1521-3773(19980316)37:5<636::AID-ANIE636>3.0.CO;2-X.
Dry air is the source of molecular nitrogen for reactions with TiL , Li, and TMSCl (L = Cl, OiPr; TMS = trimethylsilyl). The nitrogen-titanium complexes thus prepared can be used to synthesize indoles, pyrroles, and lactams from carbonyl compounds. Applying this method to 1 provides access to 2, the key compound in the synthesis of (±)-lycopodine.
干燥空气是与TiL、Li和TMSCl（L = Cl、OiPr；TMS = 三甲基硅基）发生反应的分子氮源。由此制备的氮 - 钛配合物可用于从羰基化合物合成吲哚、吡咯和内酰胺。将该方法应用于1可得到2，即(±)-石松碱合成中的关键化合物。
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