Kuzmin Julius, Margarita Cristiana, Ahumada Guillermo, Mitra Mainak, Lundberg Helena
Department of Chemistry, KTH Royal Institute of Technology, Teknikringen 30, S-100 44 Stockholm, Sweden.
Department of Chemistry, Burdwan Raj College, Purba Bardhaman, West Bengal 713104, India.
ACS Catal. 2025 Jul 21;15(15):13377-13390. doi: 10.1021/acscatal.5c03780. eCollection 2025 Aug 1.
Titanium is an earth abundant metal with low toxicity that is able to form complexes that mediate a wide range of organic transformations in both polar and radical manifolds. In context of the latter, the use of Ti-catalysts in electrosynthesis is surprisingly underexplored, considering the great potential for electrochemical (re)-generation of low-valent and catalytically active species. To spur further innovation in the field, this Review provides an overview of the current literature and discusses the limitations and possibilities for electrochemically driven Ti-catalysis.
钛是一种在地壳中储量丰富且毒性低的金属，它能够形成络合物，介导极性和自由基体系中的多种有机转化。在后者的背景下，考虑到电化学（再）生成低价和催化活性物种的巨大潜力，钛催化剂在电合成中的应用却出人意料地未得到充分探索。为推动该领域的进一步创新，本综述概述了当前的文献，并讨论了电化学驱动的钛催化的局限性和可能性。
