Schütte Markus, Kurth Dirk G, Linford Matthew R, Cölfen Helmut, Möhwald Helmut
Max-Planck-Institut für Kolloid- und Grenzflächenforschung, Rudower Chaussee 5, D-12489 Berlin-Adlershof (Germany), Fax: (+49) 30-6392-3102.
Angew Chem Int Ed Engl. 1998 Nov 2;37(20):2891-2893. doi: 10.1002/(SICI)1521-3773(19981102)37:20<2891::AID-ANIE2891>3.0.CO;2-7.
Molecular recognition and electrostatic interaction of oppositely charged polyelectrolytes are combined in the fabrication of ultrathin metallosupramolecular multilayers [shown schematically in the picture, PEI=polyethyleneimine, PSS=poly(styrene sulfonate)]. The layers between the PSS layers are composed of an iron(II) bis(terpyridine) coordination polymer.
带相反电荷的聚电解质之间的分子识别和静电相互作用被结合用于制备超薄金属超分子多层膜(如图所示,PEI = 聚乙烯亚胺,PSS = 聚(苯乙烯磺酸盐))。PSS层之间的层由铁(II)双(三联吡啶)配位聚合物组成。