Bräse Stefan, Enders Dieter, Köbberling Johannes, Avemaria Frank
Institut für Organische Chemie der Technischen Hochschule, Professor-Pirlet-Strasse 1, D-52074 Aachen (Germany), Fax: (+49) 241-8888127.
Angew Chem Int Ed Engl. 1998 Dec 31;37(24):3413-3415. doi: 10.1002/(SICI)1521-3773(19981231)37:24<3413::AID-ANIE3413>3.0.CO;2-K.
Triazenes as "traceless" linkers for solid-phase synthesis have been utilized for the attachment of arenes to a solid support and yield the corresponding products after various organometallic reactions (Heck reaction and asymmetric dihydroxylation, see the reaction scheme) and cycloadditions (Diels-Alder reaction). The triazene linker is distinguished by its accessibility, thermal robustness, and capability to undergo regeneration.
