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基于纳米掺杂基质修饰的可打印皮肤驱动的力致发光器件。

Printable Skin-Driven Mechanoluminescence Devices via Nanodoped Matrix Modification.

机构信息

Key Laboratory of Green Printing, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing Engineering Research Center of Nanomaterials for Green Printing Technology, National Laboratory for Molecular Sciences (BNLMS), Beijing, 100190, P. R. China.

University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.

出版信息

Adv Mater. 2018 Jun;30(25):e1800291. doi: 10.1002/adma.201800291. Epub 2018 May 3.

Abstract

Mechanically driven light generation is an exciting and under-exploited phenomenon with a variety of possible practical applications. However, the current driving mode of mechanoluminescence (ML) devices needs strong stimuli. Here, a flexible sensitive ML device via nanodopant elasticity modulus modification is introduced. Rigid ZnS:M (Mn/Cu)@Al O microparticles are dispersed into soft poly(dimethylsiloxane) (PDMS) film and printed out to form flexible devices. For various flexible and sensitive scenes, SiO nanoparticles are adopted to adjust the elasticity modulus of the PDMS matrix. The doped nanoparticles can concentrate stress to ZnS:M (Mn/Cu)@Al O microparticles and achieve intense ML under weak stimuli of the moving skin. The printed nano-/microparticle-doped matrix film can achieve skin-driven ML, which can be adopted to present fetching augmented animations expressions. The printable ML film, amenable to large areas, low-cost manufacturing, and mechanical softness will be versatile on stress visualization, luminescent sensors, and open definitely new functional skin with novel augmented animations expressions, the photonic skin.

摘要

机械驱动的发光是一种令人兴奋但尚未充分利用的现象,具有多种潜在的实际应用。然而,目前的机械发光(ML)器件的驱动模式需要强烈的刺激。在这里,我们介绍了一种通过纳米掺杂弹性模量修饰的柔性敏感 ML 器件。将刚性的 ZnS:M(Mn/Cu)@Al2O3 微米颗粒分散到软质聚二甲基硅氧烷(PDMS)薄膜中,并打印出来形成柔性器件。对于各种柔性和敏感的场景,可以采用 SiO2 纳米颗粒来调整 PDMS 基质的弹性模量。掺杂的纳米颗粒可以将应力集中到 ZnS:M(Mn/Cu)@Al2O3 微米颗粒上,并在皮肤的微弱运动刺激下实现强烈的 ML。打印的纳米/微米颗粒掺杂的基质膜可以实现皮肤驱动的 ML,可用于呈现引人入胜的增强动画表达。这种可打印的 ML 膜具有大面积、低成本制造和机械柔软性,将在应力可视化、发光传感器等方面具有广泛的应用,并为具有新颖增强动画表达的光子皮肤开辟全新的功能。

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