School of Materials Science and Engineering, Shenyang Jianzhu University, Shenyang 110168, China.
College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, China.
ACS Appl Mater Interfaces. 2021 Dec 22;13(50):60689-60696. doi: 10.1021/acsami.1c20505. Epub 2021 Dec 13.
Inspired by the spider's slit organ embedded in the leg joint exoskeleton and its ultrasensitive stress perception, we propose to fix the conflict between the stress concentration requirement for bright mechanoluminescence (ML) and the stress dispersion effect of soft material via integrating slit microstructures into flexible films. The designed slits focus weak stresses onto the corner to achieve high sensitivity, leading to 10-30 times ML intensity improvement at weak strain (<10% stretch) application. Slit morphology and various patterns were well investigated to address the stress distribution regularity. The slit-based ML film offers a facile light-luminescent artificial skin for visualizable stress presentations or detections without electricity power source. It is a practical endeavor of photonic skin for visible vocalization and a significant contribution to dysaudia auxiliary or luminescence augmented expressions for human social interactions, similar to jellyfish or squids.
受蜘蛛腿关节外骨骼中嵌入的缝隙器官及其对超灵敏应力感知的启发,我们通过将微缝隙结构整合到柔性薄膜中,提出了解决亮场力学发光(ML)的应力集中要求与软物质的应力分散效应之间冲突的方法。设计的缝隙将较弱的应力集中到拐角处,以实现高灵敏度,从而在弱应变(<10%拉伸)应用下将 ML 强度提高 10-30 倍。对缝隙形态和各种图案进行了很好的研究,以解决应力分布规律问题。基于缝隙的 ML 薄膜为可视化的应力演示或检测提供了一种简单的光致发光人工皮肤,无需电源。这是光子皮肤在可见发声方面的实际应用,也是对听觉障碍辅助或发光增强表达的重要贡献,类似于水母或鱿鱼。