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具有高粘结强度和耐水性的环保木纤维复合材料。

Environment-friendly wood fibre composite with high bonding strength and water resistance.

作者信息

Ji Xiaodi, Dong Yue, Nguyen Tat Thang, Chen Xueqi, Guo Minghui

机构信息

Key Laboratory of Bio-Based Material Science and Technology of the Ministry of Education, Northeast Forestry University, Harbin 150040, People's Republic of China.

出版信息

R Soc Open Sci. 2018 Apr 4;5(4):172002. doi: 10.1098/rsos.172002. eCollection 2018 Apr.

Abstract

With the growing depletion of wood-based materials and concerns over emissions of formaldehyde from traditional wood fibre composites, there is a desire for environment-friendly binders. Herein, we report a green wood fibre composite with specific bonding strength and water resistance that is superior to a commercial system by using wood fibres and chitosan-based adhesives. When the mass ratio of solid content in the adhesive and absolute dry wood fibres was 3%, the bonding strength and water resistance of the wood fibre composite reached the optimal level, which was significantly improved over that of wood fibre composites without adhesive and completely met the requirements of the Chinese national standard GB/T 11718-2009. Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) characterizations revealed that the excellent performance of the binder might partly be due to the amide linkages and hydrogen bonding between wood fibres and the chitosan-based adhesive. We believe that this strategy could open new insights into the design of environment-friendly wood fibre composites with high bonding strength and water resistance for multifunctional applications.

摘要

随着木质材料的日益枯竭以及对传统木纤维复合材料甲醛排放的担忧,人们对环保型粘合剂有了需求。在此,我们报道了一种具有特定粘结强度和耐水性的绿色木纤维复合材料,该材料通过使用木纤维和壳聚糖基粘合剂,其性能优于商业体系。当粘合剂中固含量与绝干木纤维的质量比为3%时,木纤维复合材料的粘结强度和耐水性达到最佳水平,相较于无粘合剂的木纤维复合材料有显著提高,完全符合中国国家标准GB/T 11718 - 2009的要求。傅里叶变换红外光谱(FTIR)、X射线光电子能谱(XPS)和X射线衍射(XRD)表征表明,粘合剂的优异性能可能部分归因于木纤维与壳聚糖基粘合剂之间的酰胺键和氢键。我们相信,这种策略可为设计具有高粘结强度和耐水性的多功能环保木纤维复合材料开辟新的思路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8d5/5936918/1fb38d2369d3/rsos172002-g1.jpg

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