College of Bioresources Chemical and Materials Engineering, Shaanxi Provincial Key Laboratory of Papermaking Technology and Specialty Paper Development, Shaanxi University of Science and Technology, Xi'an, 710021, China; Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education, Qilu University of Technology, Jinan, 250353, China.
College of Bioresources Chemical and Materials Engineering, Shaanxi Provincial Key Laboratory of Papermaking Technology and Specialty Paper Development, Shaanxi University of Science and Technology, Xi'an, 710021, China.
Carbohydr Polym. 2018 Aug 1;193:82-88. doi: 10.1016/j.carbpol.2018.03.089. Epub 2018 Mar 27.
A novel cellulose-based antibacterial material, namely silver nanoparticles@ metal-organic frameworks@ carboxymethylated fibers composites (Ag NPs@ HKUST-1@ CFs), was synthesized. The results showed that the metal-organic frameworks (HKUST-1) were uniformly anchored on the fiber's surfaces by virtue of complexation between copper ions in HKUST-1 and carboxyl groups on the carboxymethylated fibers (CFs). The silver nanoparticles (Ag NPs) were immobilized and well-dispersed into the pores and/or onto the surfaces of HKUST-1 via in situ microwave reduction, resulting in the formation of novel Ag NPs@ HKUST-1@ CFs composites. The antibacterial assays showed that the as-prepared composites exhibited a much higher antibacterial activity than Ag NPs@ CFs or HKUST-1@ CFs samples.
一种新型的基于纤维素的抗菌材料，即银纳米粒子@金属有机骨架@羧甲基化纤维复合材料（Ag NPs@HKUST-1@CFs）被合成。结果表明，金属有机骨架（HKUST-1）通过 HKUST-1 中的铜离子与羧甲基化纤维（CFs）上的羧基之间的络合作用均匀地锚定在纤维表面上。银纳米粒子（Ag NPs）通过原位微波还原被固定并良好地分散到 HKUST-1 的孔中和/或表面上，从而形成新型的 Ag NPs@HKUST-1@CFs 复合材料。抗菌试验表明，所制备的复合材料表现出比 Ag NPs@CFs 或 HKUST-1@CFs 样品更高的抗菌活性。
