Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu 215123, China.
Chem Commun (Camb). 2018 Jun 5;54(46):5895-5898. doi: 10.1039/c8cc01791c.
Organic molecules of DIDB can inherently assemble into fluorescent green-emissive microwires with a low photoluminescence quantum efficiency (PLQY) of 1.0%. Impressively, by doping DIDB into the nonluminous 4-iodobenzonitrile crystal matrix with a molar ratio of 1 : 100, phosphorescent yellow-emissive microwires with a much higher PLQY of 50.5% are obtained.
DIDB 的有机分子可以自发组装成发荧光绿光的微米线,其光致发光量子效率(PLQY)仅为 1.0%。令人印象深刻的是,通过将 DIDB 以摩尔比 1:100 掺杂到无发光的 4-碘苯甲腈晶体基质中,得到了磷光黄色发射的微米线,其 PLQY 高达 50.5%。