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新型多糖基吸附剂的制备及其在水净化中的应用。

Fabrication of a new polysaccharide-based adsorbent for water purification.

机构信息

Center for Molecular Metabolism, Nanjing University of Science & Technology, Nanjing 210094, China.

Center for Molecular Metabolism, Nanjing University of Science & Technology, Nanjing 210094, China.

出版信息

Carbohydr Polym. 2018 Sep 1;195:368-377. doi: 10.1016/j.carbpol.2018.04.112. Epub 2018 Apr 30.

Abstract

Expanding the application of polysaccharide material has attracted tremendous attention in the fields of wastewater treatment, agriculture and biomedical engineering, on account of its tunable and unique properties. Herein, we employ a water-soluble, sustainable and low cost bacterial polysaccharide, salecan as a matrix, poly(acrylamide-co-itaconic acid) (PAI) as a synthetic component to synthesize salecan-g-PAI hydrogels through a simple chemical crosslinking method. Their physicochemical properties were fully characterized by various methods including Fourier transformed infrared spectroscopy, X-ray diffraction, thermogravimetry, scanning electron microscope and rheometry. We found that salecan not only acted as the interaction sites to regulate the water content of the developing hydrogels, but also endowed them with tailorable morphology. The designed salecan-g-PAI hydrogels exhibited excellent adsorption properties toward methylene blue (MB) dye, and the adsorption process could be well described by the pseudo-second-order kinetic and Freundlich isotherm models. Altogether, this study broadens the application of salecan polysaccharides and provides a new device for dye decontamination.

摘要

多糖材料的应用扩展在废水处理、农业和生物医学工程等领域引起了极大的关注,这是由于其可调谐且独特的性质。在此,我们采用了一种水溶性、可持续且低成本的细菌多糖——沙菜胶作为基质,聚(丙烯酰胺-co-衣康酸)(PAI)作为合成成分,通过简单的化学交联法合成了沙莱胶-g-PAI 水凝胶。我们通过各种方法对其物理化学性质进行了充分的表征,包括傅里叶变换红外光谱、X 射线衍射、热重分析、扫描电子显微镜和流变学。我们发现,沙莱胶不仅可以作为调节水凝胶中含水量的相互作用点,还可以赋予其可调节的形态。设计的沙莱胶-g-PAI 水凝胶对亚甲基蓝(MB)染料表现出优异的吸附性能,吸附过程可以很好地用伪二阶动力学和 Freundlich 等温线模型来描述。总的来说,这项研究拓宽了沙莱胶多糖的应用范围,并为染料净化提供了一种新的装置。

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