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纳米Al₂O₃改性环氧树脂的拉伸、准静态和动态断裂性能

Tensile, Quasistatic and Dynamic Fracture Properties of Nano-Al₂O₃-Modified Epoxy Resin.

作者信息

Duan Zhiwei, He Hailing, Liang Wenyan, Wang Zhenqing, He Liang, Zhang Xiaohong

机构信息

Smart Structrues and Advanced Composite Materials Lab, Harbin Engineering University, Harbin, 150001, China.

School of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China.

出版信息

Materials (Basel). 2018 May 28;11(6):905. doi: 10.3390/ma11060905.

Abstract

Epoxy resin, modified with different particle sizes (50 nm, 100 nm, 200 nm) and contents (1 wt %, 3 wt %, 5 wt %, 7 wt %) was manufactured. The mechanical behaviors of tensile, quasistatic fracture and dynamic fracture under SHPB (split Hopkinson pressure bar) loading were investigated. The dynamic fracture behaviors of the composites were evaluated by 2D-DIC (digital image correlation) and the strain gauge technique, and the fracture surface was examined by SEM (scanning electron microscope). According to the results, the tensile modulus and strength significantly increased for epoxy resin modified with 5 wt % Al₂O₃ of 50 nm. The quasistatic fracture toughness of modified epoxy resin increased with the particle content. However, the fracture toughness of epoxy resin modified with high content fillers decreased for particle agglomeration that existed in epoxy resin. The crack propagation velocity can be decreased for epoxy resin modified with particles under dynamic loading. The dynamic initiation fracture toughness of modified epoxy resin increases with both particle size and content, but when the fillers have a high content, the particle size effects are weak. For the composite under dynamic loading conditions, the toughening mechanism is also affected by particle size.

摘要

制备了用不同粒径(50纳米、100纳米、200纳米)和含量(1重量%、3重量%、5重量%、7重量%)改性的环氧树脂。研究了其在SHPB(分离式霍普金森压杆)加载下的拉伸、准静态断裂和动态断裂力学行为。通过二维数字图像相关技术和应变片技术评估复合材料的动态断裂行为,并用扫描电子显微镜检查断口表面。结果表明,用5重量%的50纳米Al₂O₃改性的环氧树脂的拉伸模量和强度显著提高。改性环氧树脂的准静态断裂韧性随颗粒含量增加而提高。然而,由于环氧树脂中存在颗粒团聚现象,高含量填料改性的环氧树脂的断裂韧性降低。动态加载下,颗粒改性的环氧树脂的裂纹扩展速度可以降低。改性环氧树脂的动态起裂断裂韧性随颗粒尺寸和含量的增加而提高,但当填料含量较高时,颗粒尺寸效应较弱。对于动态加载条件下的复合材料,增韧机制也受颗粒尺寸影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/308b/6025226/c87f14c68177/materials-11-00905-g001.jpg

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