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二氟代-{2-[(4-羟基苯基)重氮基]-3,5-二甲基吡咯烷基}硼的晶体结构

Crystal structure of di-fluorido-{2-[(4-hy-droxy-phen-yl)diazen-yl]-3,5-di-methyl-pyrrolido}boron.

作者信息

Feng Huixiao, Yin Zhenming

机构信息

College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, People's Republic of China.

Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry, (Tianjin Normal University), Ministry of Education, Tianjin 300387, People's Republic of China.

出版信息

Acta Crystallogr E Crystallogr Commun. 2018 Apr 27;74(Pt 5):743-746. doi: 10.1107/S2056989018006229. eCollection 2018 May 1.

DOI:10.1107/S2056989018006229
PMID:29850104
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5947500/
Abstract

The asymmetric unit of the title azo-pyrrole-BF complex, CHBFNO, contains two independent mol-ecules, which are linked by an O-H⋯O hydrogen bond. The dimers are further assembled into a one-dimensional ladder-like structure through O-H⋯F hydrogen bonds and stabilized by π-π inter-actions. The ladders are further linked by C-H⋯π contacts.

摘要

标题偶氮-吡咯-BF 配合物 CHBFNO 的不对称单元包含两个独立分子，它们通过 O-H⋯O 氢键相连。这些二聚体通过 O-H⋯F 氢键进一步组装成一维梯状结构，并通过 π-π 相互作用得以稳定。这些梯子通过 C-H⋯π 接触进一步相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b65/5947500/d3b78d278ef4/e-74-00743-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b65/5947500/2ca5bcbf2fde/e-74-00743-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b65/5947500/971f66277134/e-74-00743-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b65/5947500/d3b78d278ef4/e-74-00743-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b65/5947500/2ca5bcbf2fde/e-74-00743-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b65/5947500/971f66277134/e-74-00743-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b65/5947500/d3b78d278ef4/e-74-00743-fig3.jpg

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