Kosinov Nikolay, Liu Chong, Hensen Emiel J M, Pidko Evgeny A
Inorganic Systems Engineering Group, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, Van der Maasweg 9, 2629 HZ Delft, The Netherlands.
Schuit Institute of Catalysis, Laboratory of Inorganic Materials Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Chem Mater. 2018 May 22;30(10):3177-3198. doi: 10.1021/acs.chemmater.8b01311. Epub 2018 May 7.
Transition metal-zeolite composites are versatile catalytic materials for a wide range of industrial and lab-scale processes. Significant advances in fabrication and characterization of well-defined metal centers confined in zeolite matrixes have greatly expanded the library of available materials and, accordingly, their catalytic utility. In this review, we summarize recent developments in the field from the perspective of materials chemistry, focusing on synthesis, postsynthesis modification, (operando) spectroscopy characterization, and computational modeling of transition metal-zeolite catalysts.
过渡金属-沸石复合材料是适用于广泛工业和实验室规模过程的多功能催化材料。将明确界定的金属中心限制在沸石基质中的制备和表征方面的重大进展极大地扩展了可用材料的库，相应地也扩展了它们的催化效用。在本综述中，我们从材料化学的角度总结了该领域的最新进展，重点关注过渡金属-沸石催化剂的合成、合成后修饰、（原位）光谱表征和计算建模。
