Masakado Sota, Kobayashi Yusuke, Takemoto Yoshiji
Graduate School of Pharmaceutical Sciences, Kyoto University.
Chem Pharm Bull (Tokyo). 2018;66(6):688-690. doi: 10.1248/cpb.c18-00198.
Activation of N-sulfonyliminiodinanes was achieved by photo-irradiation at 375 nm, which enabled the reaction with several alkenes to afford the corresponding aziridines. Mechanistic studies suggested that the reaction would proceed through a stepwise mechanism via radical intermediates rather than through a concerted process.
通过在375nm处进行光照射实现了N-磺酰基亚氨基碘烷的活化，这使得它能够与几种烯烃反应生成相应的氮杂环丙烷。机理研究表明，该反应将通过自由基中间体以分步机理进行，而不是通过协同过程。
