Key Laboratory of Synthetic and Natural Functional Molecule Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, 710127, P.R. China.
Chem Asian J. 2018 Sep 4;13(17):2257-2276. doi: 10.1002/asia.201800583. Epub 2018 Jul 30.
N-Heterocyclic carbenes (NHCs) have been widely employed in the construction of various metal complexes and applied in the field of catalysis. In this review, a series of palladium complexes comprising chelating bis(NHC) donors (Pd-bis(NHC) complexes) are outlined according to their application in homogeneous catalysis. Examples of metal-organic frameworks containing Pd-bis(NHC) moieties are briefly discussed, in terms of their use in heterogeneous catalysis. The catalytic applications of Pd-bis(NHC) complexes (or moieties in heterogeneous catalysts) are mainly focused on the Mizoroki-Heck, Suzuki-Miyaura, and Sonogashira coupling reactions. Another 14 types of reactions are also summarized beyond these three types of reactions.
N-杂环卡宾（NHCs）已广泛应用于各种金属配合物的构建，并应用于催化领域。在这篇综述中，根据其在均相催化中的应用，概述了一系列包含螯合双（NHC）供体的钯配合物（Pd-双（NHC）配合物）。简要讨论了含有 Pd-双（NHC）部分的金属有机骨架，根据它们在多相催化中的应用。Pd-双（NHC）配合物（或多相催化剂中的部分）的催化应用主要集中在 Mizoroki-Heck、Suzuki-Miyaura 和 Sonogashira 偶联反应上。在这三种反应之外，还总结了另外 14 种类型的反应。
