（，）-二碘代-{3,3'-亚甲基双[1-（1-羟基-4-甲基戊-2-基）咪唑-2-亚基]}钯（II）乙醇单溶剂合物
(,)-Di-iodido-{3,3'-methyl-enebis[1-(1-hy-droxy-4-methyl-pentan-2-yl)imidazol-2-ylene]}palladium(II) ethanol monosolvate.
作者信息
Liao Ping, Wang Yanping, Zhong Li, Yuan Jinwei, Yang Liangru
机构信息
School of Chemistry & Chemical Engineering Henan University of Technology,Zhengzhou 450001 People's Republic of China.
School of Energy and Chemical Engineering, Puyang Vocational and Technical, College, Puyang 457001, People's Republic of China.
出版信息
IUCrdata. 2025 Jun 10;10(Pt 6):x250423. doi: 10.1107/S2414314625004237. eCollection 2025 Jun.
The structure of the title solvated bis--heterocyclic carbene palladium(II) complex, [PdI(CHNO)·CHO, exhibits a slightly distorted square-planar coord-in-ation at the palladium(II) atom, with the six-membered chelate ring adopting a boat conformation. One disordered ethanol solvent mol-ecule was co-crystallized. There are inter-molecular O-H⋯O hydrogen bonds in the structure. The chiral centers of the precursor imidazolium salt was preserved during the metalation process.
标题溶剂化双杂环卡宾钯（II）配合物[PdI(CHNO)·CHO]的结构在钯（II）原子处呈现出略微扭曲的平面正方形配位，六元螯合环呈船式构象。一个无序的乙醇溶剂分子共结晶。结构中存在分子间O-H⋯O氢键。前体咪唑盐的手性中心在金属化过程中得以保留。
Zotero 插件