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采用数学方法从磨铁金矿废水中选择合适的方法去除氰化物。

Selecting an appropriate method to remove cyanide from the wastewater of Moteh gold mine using a mathematical approach.

机构信息

Mining Department, Faculty of Engineering, Lorestan University, Khorram Abad, Lorestan, Iran.

出版信息

Environ Sci Pollut Res Int. 2018 Aug;25(23):23357-23369. doi: 10.1007/s11356-018-2424-1. Epub 2018 Jun 5.

Abstract

The presence of cyanide ions in wastewater is dangerous to the health and life of living creatures, especially humans. Cyanide concentration should not exceed the acceptable limit in wastewaters to avoid their adverse effects to the environment. In this paper, in order to select the most appropriate method to remove cyanide from the wastewater of the Moteh gold mine, based on the experts' opinions, the use of calcium hypochlorite, sodium hypochlorite, and hydrogen peroxide was chosen as forerunning alternative in the form of a multi-stage model. Then, seven criteria including the amount of material consumed, ease of implementation, safety, ability to remove cyanide, pH, time, and cost of the process to assess the considered methods were determined. Afterwards, seven experts conducted numerous experiments to examine the conditions of each of these criteria. Then, by employing a mathematical method called "numerical taxonomy," the use of sodium hypochlorite was suggested as the best method to remove cyanide from the wastewater of the Moteh gold mine. Finally, the TOPSIS model was used to validate the proposed model, which led to the same results of the suggested method. Also, the results of employing taxonomic analysis and TOPSIS method suggested the use of sodium hypochlorite as the best method for cyanide removal from wastewater. In addition, according to the analysis of various experiments, conditions for complete removal of cyanide using sodium hypochlorite included concentration (8.64 g/L), pH (12.3), and temperature (12 °C).

摘要

废水中氰化物离子的存在对生物的健康和生命构成威胁,尤其是对人类。氰化物浓度不应超过废水中的可接受限值,以避免对环境产生不利影响。在本文中,为了选择从 Motah 金矿废水中去除氰化物的最合适方法,根据专家意见,选择了以多阶段模型的形式使用次氯酸钙、次氯酸钠和过氧化氢作为先行替代方法。然后,确定了七种标准,包括材料消耗、实施难易程度、安全性、去除氰化物的能力、pH 值、时间和工艺成本,以评估所考虑的方法。之后,七位专家进行了多次实验,以检验这些标准的条件。然后,通过使用一种称为“数值分类法”的数学方法,建议使用次氯酸钠作为去除 Motah 金矿废水中氰化物的最佳方法。最后,使用 TOPSIS 模型验证了所提出的模型,结果表明建议的方法是最佳方法。此外,分类分析和 TOPSIS 方法的结果表明,使用次氯酸钠是从废水中去除氰化物的最佳方法。另外,根据对各种实验的分析,使用次氯酸钠完全去除氰化物的条件包括浓度(8.64 g/L)、pH 值(12.3)和温度(12°C)。

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