State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, Laboratory of Special Function Materials and Structure Design of the Ministry of Education, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China.
Chem Commun (Camb). 2018 Jun 21;54(51):7046-7049. doi: 10.1039/c8cc03112f.
Well-ordered NiFe-MOF-74 is in situ grown on Ni foam by the induction of Fe2+ and directly used as an OER electrocatalyst. Benefited from the intrinsic open porous structure of MOF-74, the in situ formed MOF arrays and the synergistic effect of Ni and Fe, outstanding water oxidation activity is obtained in alkaline electrolytes with an overpotential of 223 mV at 10 mA cm-2.
有序的 NiFe-MOF-74 通过 Fe2+ 的诱导在 Ni 泡沫上原位生长，并直接用作 OER 电催化剂。得益于 MOF-74 的固有开放多孔结构、原位形成的 MOF 阵列和 Ni 与 Fe 的协同作用，在碱性电解液中获得了出色的水氧化活性，在 10 mA cm-2 时的过电位为 223 mV。
