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用于高效电催化析氧反应的镍（II）基配位聚合物。

Ni(ii)-based coordination polymers for efficient electrocatalytic oxygen evolution reaction.

作者信息

Jiang Zhi-Qiang, Li Yu-Feng, Zhu Xue-Jun, Lu Jin, Zhang Lei, Wen Tian

机构信息

Deep-processing of Fine Flake Graphite Sichuan Province Key Laboratory of Colleges and Universities, Panzhihua University Panzhihua Sichuan 617000 P. R. China

School of Chemistry, The University of Melbourne Parkville Victoria 3010 Australia

出版信息

RSC Adv. 2018 Nov 15;8(67):38562-38565. doi: 10.1039/c8ra07492e. eCollection 2018 Nov 14.

DOI:10.1039/c8ra07492e
PMID:35559078
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9090564/
Abstract

The exploration of highly efficient, stable and cheap water oxidation electrocatalysts using earth-abundant elements is still a great challenge. Herein, alkaline-stable cationic Ni(ii) coordination polymers (Ni-CPs) were successfully obtained under hydrothermal conditions, which could stabilize the incorporation of Fe(iii) to form Fe-immobilized Fe@Ni-CPs. The newly developed Ni-based CPs were used for the first time as an effective electrocatalyst for the oxygen evolution reaction in strong alkaline media.

摘要

利用储量丰富的元素探索高效、稳定且廉价的水氧化电催化剂仍然是一个巨大的挑战。在此，在水热条件下成功获得了碱性稳定的阳离子镍（II）配位聚合物（Ni-CPs），其能够稳定铁（III）的掺入以形成铁固定化的Fe@Ni-CPs。新开发的镍基配位聚合物首次被用作强碱性介质中析氧反应的有效电催化剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/128ab0dd80e0/c8ra07492e-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/f7ff2b35d8f1/c8ra07492e-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/cd31ecba2303/c8ra07492e-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/b1dbd2b6a006/c8ra07492e-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/527da34a8cd4/c8ra07492e-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/128ab0dd80e0/c8ra07492e-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/f7ff2b35d8f1/c8ra07492e-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/cd31ecba2303/c8ra07492e-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/b1dbd2b6a006/c8ra07492e-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/527da34a8cd4/c8ra07492e-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45b3/9090564/128ab0dd80e0/c8ra07492e-f4.jpg

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