锰催化的对醌甲川的 1,6-共轭加成/芳构化。
Mn-Catalyzed 1,6-conjugate addition/aromatization of para-quinone methides.
机构信息
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, China.
出版信息
Org Biomol Chem. 2018 Jun 20;16(24):4547-4557. doi: 10.1039/c8ob01057a.
A series of ferrocenyl triazole ligands have been synthesized and characterized, which proved to be effective for the Mn-catalyzed 1,6-conjugate addition/aromatization of para-quinone methides with good to high yields under mild conditions. This protocol provided an efficient and practical route to the synthetically interesting functionalized quinones, methines and their analogues.
已经合成并表征了一系列二茂铁基三唑配体，这些配体被证明在温和条件下对 Mn 催化的对醌甲基化物的 1,6-共轭加成/芳构化反应非常有效，产率良好至高产。该方案为具有合成意义的功能化醌、亚甲二氧基及其类似物提供了一种有效且实用的合成途径。
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