铜催化合成 2,2-二氟-1,3-苯并氧硫杂环戊烯（硒杂环戊烯）及其杀虫活性：硒效应。
Copper-catalyzed synthesis of 2,2-difluoro-1,3-benzoxathioles(selenoles) and their insecticidal activities: the selenium effect.
机构信息
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350108, China.
出版信息
Org Biomol Chem. 2018 Jun 20;16(24):4558-4562. doi: 10.1039/c8ob01254g.
PMID:29877541
Abstract
An efficient catalytic method for the synthesis of 2,2-difluoro-1,3-benzoxathioles(selenoles) from the reaction of o-bromophenols with trifluoromethanethiolates or selenolates is disclosed. Some of the title compounds exhibited excellent insecticidal activities.
摘要
本文报道了一种从邻溴苯酚与三氟甲硫醇盐或硒醇盐反应合成 2,2-二氟-1,3-苯并恶硫（硒）唑的高效催化方法。部分标题化合物表现出优异的杀虫活性。
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