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食品中的矿物油碳氢化合物:综述

Mineral oil hydrocarbons in food: a review.

作者信息

Grob Koni

机构信息

a Kantonales Labor Zürich (Official Food Control Authority of the Canton of Zürich) , Zürich , Switzerland.

出版信息

Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2018 Sep;35(9):1845-1860. doi: 10.1080/19440049.2018.1488185. Epub 2018 Jul 24.

DOI:10.1080/19440049.2018.1488185
PMID:29894283
Abstract

Work on mineral oil hydrocarbons (MOH) contaminating food is reviewed up to about 2010, when the subject received broad publicity. It covers the period of the main discoveries and elimination or reduction of the dominant sources: release agents used in industrial bakeries, spraying of rice, additions to animal feed, contamination of edible oils from various sources and migration from paperboard packaging. In most cases, highly refined ('white') oils were involved, but also technical oils, e.g. from the environment, and more or less crude oil fractions from jute and sisal bags. There were numerous unexpected sources, and there might still be more of those. The exposure of the consumers to MOH must have been markedly reduced in the meantime. Environmental influx may have become dominant, particularly when taking into account that these MOH go through several degradation processes which might enrich the species resisting metabolic elimination. Major gaps are in the systematic investigation of sources and the largely unavoidable levels from environmental contamination, but also in the toxicological evaluation of the various types of hydrocarbons. A regulation is overdue that avoids the present discrepancy between the low tolerance to MOH perceived as contaminants and the very high legal limits for some applications - the MOH are largely the same.

摘要

本文回顾了截至2010年左右关于矿物油碳氢化合物(MOH)污染食品的研究工作,当时该主题受到了广泛关注。它涵盖了主要发现以及主要污染源的消除或减少时期:工业面包店使用的脱模剂、大米喷洒、动物饲料添加、各种来源食用油的污染以及纸板包装的迁移。在大多数情况下,涉及的是高度精炼的(“白色”)油,但也有工业用油,例如来自环境的油,以及来自黄麻和剑麻袋的或多或少的原油馏分。有许多意想不到的来源,而且可能还有更多。与此同时,消费者接触MOH的情况肯定已显著减少。环境流入可能已占主导地位,特别是考虑到这些MOH会经历几个降解过程,这可能会使抗代谢消除的物种富集。主要差距在于对来源的系统调查以及环境污染带来的基本上不可避免的水平,还在于对各类碳氢化合物的毒理学评估。早就应该出台一项法规,以避免目前对被视为污染物的MOH的低容忍度与某些应用的非常高的法定限值之间的差异——这些MOH在很大程度上是相同的。

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