通过不对称烯丙基硼化反应对同丙烯基醇的对映选择性合成。
Enantioselective Syntheses of Homopropargylic Alcohols via Asymmetric Allenylboration.
机构信息
Department of Chemistry and Biochemistry , Auburn University , Auburn , Alabama 36849 , United States.
出版信息
Org Lett. 2018 Jul 6;20(13):3810-3814. doi: 10.1021/acs.orglett.8b01399. Epub 2018 Jun 13.
PMID:29897243
Abstract
A chiral phosphoric acid catalyzed allenylboration reaction is reported. Homopropargyl alcohols with an internal alkyne unit were obtained in good yields with high enantioselectivities under the developed conditions.
摘要
手性磷酸催化的烯丙基硼化反应被报道。在开发的条件下，具有内部炔烃单元的同丙烯基醇以高对映选择性得到了良好的产率。
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