Departamento de Física, Universidad del Valle, A.A. 25360, Cali, Colombia.
CICBA, Universidad Antonio Nariño-Campus Farallones, Km 18 vía Cali-Jamundí, Cali, Colombia.
Phys Rev E. 2018 May;97(5-1):052802. doi: 10.1103/PhysRevE.97.052802.
We study the effect of hindered aggregation on the island formation processes for a one-dimensional model of epitaxial growth with arbitrary nucleus size i. In the proposed model, the attachment of monomers to islands is hindered by an aggregation barrier, ε_{a}, which decreases the hopping rate of monomers to the islands. As ε_{a} increases, the system exhibits a crossover between two different regimes; namely, from diffusion-limited aggregation to attachment-limited aggregation. The island size distribution, P(s), is calculated for different values of ε_{a} by a self-consistent approach involving the nucleation and aggregation capture kernels. The results given by the analytical model are compared with those from kinetic Monte Carlo simulations, finding a close agreement between both sets of data for all considered values of i and ε_{a}. As the aggregation barrier increases, the spatial effect of fluctuations on the density of monomers can be neglected and P(s) smoothly approximates to the limit distribution P(s)=δ_{s,i+1}. In the crossover regime the system features a complex and rich behavior, which can be explained in terms of the characteristic timescales of different microscopic processes.
我们研究了受阻聚集对具有任意核大小 i 的外延生长一维模型中岛屿形成过程的影响。在所提出的模型中,单体附着到岛屿受到聚集势垒 ε_{a}的阻碍,这降低了单体向岛屿的跃迁速率。随着 ε_{a}的增加,系统表现出两种不同状态之间的交叉;即从扩散限制聚集到附着限制聚集。通过涉及成核和聚集捕获核的自洽方法,计算了不同 ε_{a}值下的岛大小分布 P(s)。分析模型给出的结果与动力学蒙特卡罗模拟的结果进行了比较,发现对于考虑的所有 i 和 ε_{a}值,两组数据之间都非常吻合。随着聚集势垒的增加,波动对单体密度的空间影响可以忽略不计,并且 P(s)可以平滑地近似为极限分布 P(s)=δ_{s,i+1}。在交叉区域,系统表现出复杂而丰富的行为,可以根据不同微观过程的特征时间尺度来解释。