Electrospun Single Crystalline Fork-Like KVO as High-Performance Cathode Materials for Lithium-Ion Batteries.

Single crystalline fork-like potassium vanadate (KVO) has been successfully prepared by electrospinning method with a subsequent annealing process. The as-obtained KVO forks show a unique layer-by-layer stacked structure. When used as cathode materials for lithium-ion batteries, the as-prepared fork-like materials exhibit high specific discharge capacity and excellent cyclic stability. High specific discharge capacities of 200.2 and 131.5 mA h g can be delivered at the current densities of 50 and 500 mA g, respectively. Furthermore, the KVO electrode exhibits excellent long-term cycling stability which maintains a capacity of 108.3 mA h g after 300 cycles at 500 mA g with a fading rate of only 0.043% per cycle. The results demonstrate their potential applications in next-generation high-performance lithium-ion batteries.