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改性三水合醋酸钠的制备及性能分析

Preparation and Performance Analysis of Modified Sodium Acetate Trihydrate.

作者信息

Hua Weisan, Zhang Xuelai, Muthoka Munyalo Jotham, Han Xingchao

机构信息

Institute of Thermal Storage Technology, Merchant Marine College, Shanghai Maritime University, Shanghai 201306, China.

出版信息

Materials (Basel). 2018 Jun 15;11(6):1016. doi: 10.3390/ma11061016.

Abstract

In order to solve undercooling and phase separation of sodium acetate trihydrate (SAT), experimental screening method was used to select nucleating agents and thickeners that are suitable for SAT, and the optimal ratio was identified. Through screening experiments of nucleating agents, it is found that disodium hydrogen phosphate can be used as an effective nucleating agent for SAT. When the weight content of disodium hydrogen phosphate in SAT is 2%, the degree of undercooling was reduced to approximately 2 K. The addition of 1⁻1.5% (weight) of xanthan gum (XG) to SAT can effectively inhibit the phase separation. Since the properties of SAT changes after the modification, the corresponding comparison analysis was performed. The results showed that XG has a significant influence on the SAT performance of SAT. With the addition of 1.5 wt % of XG in pure SAT, the latent heat of fusion and solid/liquid volume expansion reduce by 5.2% and 5.4% respectively, and the thermal conductivity and solid/liquid density also decreases accordingly.

摘要

为了解决三水合醋酸钠(SAT)的过冷和相分离问题,采用实验筛选方法来选择适合SAT的成核剂和增稠剂,并确定了最佳比例。通过成核剂的筛选实验,发现磷酸氢二钠可作为SAT的有效成核剂。当SAT中磷酸氢二钠的重量含量为2%时,过冷度降低至约2K。向SAT中添加1⁻1.5%(重量)的黄原胶(XG)可有效抑制相分离。由于改性后SAT的性能发生了变化,因此进行了相应的对比分析。结果表明,XG对SAT的性能有显著影响。在纯SAT中添加1.5wt%的XG时,熔化潜热和固/液体积膨胀分别降低5.2%和5.4%,热导率和固/液密度也相应降低。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ab1f/6024958/9ca10cc3fb26/materials-11-01016-g001.jpg

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