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氧化锌-石墨烯复合材料的高光催化活性。

High photocatalytic activity of ZnO-graphene composite.

机构信息

Chollege of Chemistry, Beijing Normal University, Beijing 100875, China.

出版信息

J Colloid Interface Sci. 2018 Nov 1;529:306-313. doi: 10.1016/j.jcis.2018.04.040. Epub 2018 Apr 10.

Abstract

In this work, ZnO nanoparticles-reduced graphene oxide (rGO) composites were fabricated via a novel one-step photochemical method. The developed nanocomposite offered high photodegradation efficiency of methylene blue (MB) under UV and visible light. In the proposed route, the reduction of graphene oxide (GO) and formation of ZnO nanoparticles occurred simultaneously, which results in high synthesis efficiency of ZnO/rGO nanocomposites. The electron microscopy confirmed that the ZnO nanoparticles were uniformly anchored on rGO sheets. The structure and quality of prepared nanocomposite were assessed by X-ray diffraction, Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). Furthermore, the synthesis of the nanocomposite and degradation of MB, along with a mechanistic insight, is discussed in detail.

摘要

在这项工作中,通过一种新颖的一步光化学方法制备了氧化锌纳米粒子还原氧化石墨烯(rGO)复合材料。所开发的纳米复合材料在紫外光和可见光下提供了对亚甲基蓝(MB)的高效光降解效率。在所提出的方法中,氧化石墨烯(GO)的还原和氧化锌纳米粒子的形成同时发生,这导致了 ZnO/rGO 纳米复合材料的高合成效率。电子显微镜证实,氧化锌纳米粒子均匀地锚定在 rGO 片上。通过 X 射线衍射、傅里叶变换红外(FT-IR)光谱、拉曼光谱和 X 射线光电子能谱(XPS)评估了所制备的纳米复合材料的结构和质量。此外,详细讨论了纳米复合材料的合成以及 MB 的降解及其机理。

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