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在评估地中海泻湖恢复后的痕量金属污染和生物可利用性方面,地球化学和矿物学指标有多大用处?

How useful are geochemical and mineralogical indicators in assessing trace metal contamination and bioavailability in a post-restoration Mediterranean lagoon?

机构信息

Laboratoire des Géosciences, Ressources Minérales, Energétiques, Environnement, Département de Géologie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092, Tunis, Tunisia.

Société de Promotion du Lac de Tunis, BP. No. 36, 1080, Tunis Cedex, Tunisia.

出版信息

Environ Sci Pollut Res Int. 2018 Sep;25(25):25045-25059. doi: 10.1007/s11356-018-2575-0. Epub 2018 Jun 23.

DOI:10.1007/s11356-018-2575-0
PMID:29934833
Abstract

Tunis's Lake North (LNT), located on the Mediterranean Sea, and Tunisia's most important lagoon due to its economic value and its strategic position within the city, has recently undergone a vast sanitation project. To study the lagoon's level of metal pollution, three sediment cores were taken and the sediments were analyzed for trace and major elements, acid volatile sulfides (AVS), total organic carbon (TOC), and minerals. Results showed that TOC concentrations (0.2-3.1%) decreased following the lagoon's restoration. In addition, in comparison to historical data, concentrations of Cu (16-69.5 μg g), Zn (60.6-191.4 μg g), and Pb (13-100.9 μg g1) also decreased. Enrichment factor calculation with respect to the crust and local background showed that the sediment had long been contaminated by human pollution and especially by Pb, Zn, and Cu. The AVS to simultaneously extracted metal (SEM) ratio revealed values generally less than 1 indicating no sediment toxicity risks. Statistics revealed a detrital origin for certain metals and a diagenetic origin for FeS and carbonate minerals.

摘要

突尼斯的北部泻湖(LNT)位于地中海,是突尼斯最重要的泻湖,由于其经济价值和在城市中的战略地位,该泻湖最近进行了一项大规模的卫生项目。为了研究泻湖的金属污染水平,采集了三个沉积物岩芯,并对痕量和主要元素、酸可挥发性硫化物(AVS)、总有机碳(TOC)和矿物质进行了分析。结果表明,TOC 浓度(0.2-3.1%)在泻湖修复后下降。此外,与历史数据相比,Cu(16-69.5μg/g)、Zn(60.6-191.4μg/g)和 Pb(13-100.9μg/g)的浓度也有所降低。与地壳和当地背景的富集因子计算表明,沉积物长期受到人为污染的影响,特别是受到 Pb、Zn 和 Cu 的污染。同时提取金属的 AVS(SEM)比值表明,该比值通常小于 1,表明没有沉积物毒性风险。统计数据显示,某些金属具有碎屑来源,而 FeS 和碳酸盐矿物具有成岩来源。

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本文引用的文献

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Environ Sci Pollut Res Int. 2018 Jan;25(3):2248-2264. doi: 10.1007/s11356-017-0529-6. Epub 2017 Nov 8.
2
Distribution and assessment of heavy metal toxicity in sediment cores from Bizerte Lagoon, Tunisia.突尼斯比塞大泻湖沉积物岩芯中重金属毒性的分布与评估
Environ Monit Assess. 2017 Jul;189(7):356. doi: 10.1007/s10661-017-6073-5. Epub 2017 Jun 27.
3
Trace element accumulation and elutriate toxicity in surface sediment in northern Tunisia (Tunis Gulf, southern Mediterranean).
突尼斯北部(地中海南部突尼斯湾)表层沉积物中的微量元素积累与淋出毒性
Mar Pollut Bull. 2017 Mar 15;116(1-2):216-225. doi: 10.1016/j.marpolbul.2016.12.076. Epub 2017 Jan 9.
4
3D modeling of phytoplankton seasonal variation and nutrient budget in a southern Mediterranean Lagoon.地中海南部泻湖浮游植物季节性变化及营养收支的三维建模
Mar Pollut Bull. 2017 Jan 30;114(2):962-976. doi: 10.1016/j.marpolbul.2016.11.001. Epub 2016 Nov 19.
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Structuring factors of the spatio-temporal variability of macrozoobenthos assemblages in a southern Mediterranean lagoon: How useful for bioindication is a multi-biotic indices approach?地中海南部泻湖大型底栖动物群落时空变异性的构建因素:多生物指数方法对生物指示有多大用处?
Mar Pollut Bull. 2017 Jan 15;114(1):515-527. doi: 10.1016/j.marpolbul.2016.10.023. Epub 2016 Oct 13.
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Bioavailability and assessment of heavy metal pollution in sediment cores off the Mejerda River Delta (Gulf of Tunis): How useful is a multiproxy approach?梅杰达河三角洲(突尼斯湾)沉积物岩芯中重金属污染的生物有效性评估:多指标方法有多有用?
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